Chemistry of inorganic compounds – Carbon or compound thereof – Oxygen containing
Patent
1975-11-28
1977-03-01
Vertiz, Oscar R.
Chemistry of inorganic compounds
Carbon or compound thereof
Oxygen containing
423422, C01D 716
Patent
active
040102432
ABSTRACT:
A process is provided for converting potassium chloride to potassium bicarbonate with desirable conversions which bicarbonate can then be calcined to potassium carbonate. In one embodiment the potassium bicarbonate is formed in a reaction medium which is an admixture of water and a water miscible alcohol with the other reactants employed being carbon dioxide and an alkylamine. In a more preferred embodiment an alcoholic solution of an alkylamine which solution is saturated with carbon dioxide will be prepared and then an aqueous solution of a potassium halide, preferably potassium chloride, will be added to the alcoholic solution so as to form potassium bicarbonate.
REFERENCES:
patent: 2752222 (1956-06-01), Birman
patent: 2768060 (1956-10-01), Follows
patent: 2782093 (1957-02-01), Hulot et al.
patent: 2913310 (1959-11-01), Sandborn et al.
patent: 3122173 (1963-11-01), Wolstein
patent: 3347623 (1967-10-01), Schmid
Holler Edward J.
Owens--Illinois, Inc.
Rywalski Robert F.
Straub Gary P.
Vertiz Oscar R.
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