Preparation and use of a heterogeneous rhodium catalyst for...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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C502S155000, C568S434000

Reexamination Certificate

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07087548

ABSTRACT:
A process for preparing an Rh-based catalytic system heterogenized on an organic or mineral support, characterized in that: a) a rhodium derivative with a valency state>0 is reduced in an ether or aromatic solvent and in the presence of a compound chosen from the group consisting of lipophilic tertiary amines, lipophilic tertiary amides and lipophilic quaternary ammonium salts, and b) the mixture thus obtained is adsorbed onto a suitable organic or mineral support. Use of the abovementioned catalytic system to hydrogenate a C═C double bond of an α,β-unsaturated carbonyl compound.

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International Search Report issued on PCT/EP02/11885 of which present application is the U.S. National Stage Application.

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