Precipitation of aluminum oxide having low sodium oxide content

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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423121, 423127, C01F 714

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active

040149854

ABSTRACT:
Aluminum oxide having a sodium oxide content after calcination of less than 0.1% by weight is continuously precipitated as aluminum hydroxide from a Bayer process liquor by a controlled slow precipitation. The controlled, slow precipitation rate required to create a low soda product is achieved by controlling the residence time of liquor in the precipitation vessel so as to provide a constant, low ratio of aluminum oxide to sodium oxide. Residence time control in a Bayer process plant is achieved by controlling green liquor flow rate to the tank, or by sizing the tank for a constant flow. The use of heavy seed charges to increase the seed surface area permits the production of a low soda product at a faster precipitation rate.

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patent: 3265466 (1966-08-01), Mollard
patent: 3486850 (1969-12-01), Day
patent: 3545923 (1970-12-01), Mercier et al.
patent: 3649184 (1972-03-01), Featherson

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