Power generation wherein sulfur and nitrogen oxides are removed

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

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Details

423244, 423564, 423573G, 431 4, 122 4D, B01J 800, C01B 2100, C01B 1700

Patent

active

040396215

ABSTRACT:
A sulfur bearing carbonaceous fuel, particularly a low BTU gaseous fuel, is burned in a deficiency of air in the combustion zone of a boiler to form a reducing gas containing H.sub.2 and CO in an amount in excess of that required to reduce the generated SO.sub.x to H.sub.2 S and COS. The oxides of sulfur and nitrogen are, in part, converted to H.sub.2 S, N.sub.2 and/or NH.sub.3 during heat transfer in the boiler. The balance is passed through a catalyst chamber where sulfur species are converted to H.sub.2 S and oxides of nitrogen to N.sub.2 and/or NH.sub.3. The formed H.sub.2 S is extracted from the flue gas prior to venting to the atmosphere and recovered as free sulfur. Catalytic conversion is carried out at a temperature from about 300.degree. to 800.degree. F.

REFERENCES:
patent: 3418258 (1968-12-01), Ackermann
patent: 3454355 (1969-07-01), Ryason
patent: 3752877 (1973-08-01), Beavon
patent: 3755550 (1973-08-01), Stiles
patent: 3794710 (1974-02-01), Merrill
patent: 3838193 (1974-09-01), Kajitani et al.

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