Potassium monopersulfate triple salt with increased active...

Chemistry of inorganic compounds – Sulfur or compound thereof – Oxygen containing

Reexamination Certificate

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C252S186270, C252S186430

Reexamination Certificate

active

07090820

ABSTRACT:
A method of preparing a potassium monopersulfate composition is presented, wherein the potassium monopersulfate composition has the formula (KHSO5)x(KHSO4)y(K2SO4)z, where x+y+z=1 and x=0.46–0.64, y=0.15–0.37, and z=0.15–0.37, said potassium monopersulfate composition having an active oxygen content greater than or equal to 4.9 wt. % and K2S2O8at a concentration of <0.5 wt. % of the potassium monopersulfate composition. The method includes reacting an H2O2solution containing at least 70 wt. % H2O2with a H2SO4solution at a substoichiometric ratio of the H2SO4to H2O2to generate a weak Caro's acid solution, then combining the weak Caro's acid solution with oleum to produce a rich Caro's acid solution. The rich Caro's acid solution may be combined with an alkali potassium compound to produce the potassium monopersulfate composition. During the process, the temperature is maintained at below 30 ° C.

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International Search Report and Written Opinion of the International Searching Authority for International application No. PCT/US04/31625 dated Jan. 18, 2006.

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