Positive-working O-quinone diazide photoresist composition with

Radiation imagery chemistry: process – composition – or product th – Diazo reproduction – process – composition – or product – Composition or product which contains radiation sensitive...

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430192, 430193, G03C 160

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active

047389150

ABSTRACT:
The invention provides an improvement over the conventional positive-working photoresist compositions comprising a novolac resin and an ester compound between 2,3,4-trihydroxybenzophenone and naphthoquinone-1,2-diazido-5-sulfonic acid in respect of scum formation in development and resistance of the patterned photoresist layer against heat and dry etching. The inventive composition comprises, in addition to the novolac resin and the ester compounds, 2,3,4-trihydroxybenzophenone in a specified amount relative to the ester compounds as a part of the photosensitive component which may be a reaction product obtained by the esterification reaction for the synthesis of the ester compounds containing unesterified 2,3,4-trihydroxybenzophenone.

REFERENCES:
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patent: 3148983 (1964-09-01), Endermann et al.
patent: 3402044 (1968-09-01), Steinhoff et al.
patent: 4275139 (1981-06-01), Stahlhofen
patent: 4499171 (1985-02-01), Hosaka et al.
patent: 4626492 (1986-12-01), Eilbeck
Carothers, J. A., IBM Technical Disclosure Bulletin, vol. 20, No. 9, 2/1978, p. 3569.

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