Compositions: ceramic – Ceramic compositions – Devitrified glass-ceramics
Patent
1987-03-06
1989-05-02
Lieberman, Allan M.
Compositions: ceramic
Ceramic compositions
Devitrified glass-ceramics
501 68, 435176, 43524023, C04B 3804, C12N 1114, C12N 500
Patent
active
048267899
ABSTRACT:
A particulate porous material suitable for use as a high surface area column packing material comprises particles substantially all of which are not smaller than 5 micrometers and not larger than 1 millimeter in diameter, and each particle is in the form of a substantially cellular body and consists predominantly of an open, three-dimensional matrix of crystals of mullite which define between them interconnecting pores having a width in the range of from 5 nanometers to about 2 micrometers. The particles can be coated with a reactive layer. There is also disclosed a process for producing the particulate porous material wherein a particulate product comprising particles substantially all of which are between 5 micrometers and 1 millimeter in diameter and consisting predominantly of a mixture of mullite crystals and silica is treated with a concentrated aqueous solution of an alkali metal hydroxide at a temperature of at least 50.degree. C.; and the treated particulate product is then washed, dewatered and dried. The particulate porous material may be used as a packing material for a chromatographic or ion exchange column, or for performing biochemical separations, and is particularly useful for immobilizing biological components such as biological macromolecules or biological cells.
REFERENCES:
patent: 2536122 (1951-01-01), Beriorelli et al.
patent: 3951677 (1976-04-01), Jacobson et al.
patent: 4389385 (1983-06-01), Ramsay
patent: 4415631 (1983-11-01), Schotijser
patent: 4517241 (1985-05-01), Alfert
Chem. Abstracts, 98, No. 14, Apr. 1983, p. 143, No. 109877r.
Gould Caryl
Jones Thomas R.
ECC International Limited
Lieberman Allan M.
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