Porous crystalline material (ITQ-21) and the method of...

Chemistry of inorganic compounds – Zeolite – Structure defined x-ray diffraction pattern

Reexamination Certificate

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C423S706000, C423S708000, C423S329100, C423S594900, C423S618000

Reexamination Certificate

active

07008612

ABSTRACT:
The invention relates to a porous crystalline material which, in the calcined state, has a composition: X2O3:nYO2:mZO2, wherein: X represents a trivalent element; Z represents Ge; and Y represents at least one tetravalent element other than Ge. Furthermore, in the chemical composition, (n+m) is equal to at least 5 and the Y/Z ratio is equal to at least 1. Moreover, in the calcined state, said material has an X-ray diffraction pattern which coincides substantially with (1), wherein VS is a very strong relative intensity corresponding to a percentage of between 80 and 100 with respect to the most intense peak; M is a mean relative intensity corresponding to a percentage of between 40 and 60 with respect to the most intense peak; and W is a mean relative intensity corresponding to a percentage of between 20 and 40 with respect to the most intense peak.

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patent: WO 02/092511 (2002-11-01), None
Barrett, P.A.; Synthesis in fluoride and hydroxide media and structure of the extra-large pore pure silica zeolite CIT-S; Journal of the Chemical Society, Faraday Transactions, 1998, vol. 94, No. 16, pp. 2475-2481, ISSN 0956-5000.
Lobo, R.F. et al; Synthesis and characterization of pure-silica and boron-substituted SSZ-24 using N(16) methylsparteinium bromide as structure-directing agent; Microporous Meterials 3(1994), pp. 61-69.
Tsuji, K. et al; High-silica molecular sieve synthesis using the sparteine related compounds as structure-directing agents; Microporous and Mesoporous Materials 28 (1999), pp. 461-469; ISSN 1387-1811.

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