Polyviologen modified electrode and use thereof

Details Polyviologen modified electrode and use thereof Polyviologen modified electrode and use thereof

1991-08-21

1993-08-03

Niebling, John

Chemistry: electrical and wave energy

Apparatus

Electrolytic

204416, 204290R, 204 59R, 204 72, G01H 2726

Patent

active

052325741

ABSTRACT:
A polyviologen modified electrode which comprises an insoluble film of polyviologen polymerized on a base electrode by electrochemical reduction and electrodeposition of monomer represented by the formula (I) ##STR1## Wherein R.sup.1 is a divalent group selected from the groups consisting of alkylene, cycloalkylene, arylene and arylalkylene or a trivalent group selected from the groups consisting of alkanetriyl, cycloalkanetriyl, arylalkanetriyl and aryltriyl; X.sup.- is a counter anion; m is 2 or 3, which electrode has no performance problem in connection with the solubility to water and organic solvent and the annealing phenomenon.

REFERENCES:
patent: 3856714 (1974-12-01), Moore et al.
patent: 4439302 (1984-03-01), Wrighton et al.
patent: 4545382 (1985-10-01), Higgins et al.
patent: 4895705 (1990-01-01), Wrighton et al.
patent: 4945045 (1990-07-01), Forrest et al.
patent: 4978610 (1990-12-01), Forrest et al.

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