Polyurethanes from dialkyl diaminobenzenes and processes therefo

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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252182, 264 51, 2643281, 2643286, 2643288, 521159, 521163, 528 64, 528 76, 528 83, C08G 1814

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045269050

ABSTRACT:
Dialkyl diamines for use with polyols and polyisocyanates in cast elastomer and reaction injection molding polyurethane processes. The dialkyl diamines are prepared by nitration and reduction of dialkylbenzenes or alkylation of meta-phenylenediamine. The chain extenders have the following structure: ##STR1## where R.sub.1 is C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.6 cycloalkyl and R.sub.2 is C.sub.2 -C.sub.6 alkyl or C.sub.3 -C.sub.6 cycloalkyl.
Contrary to the teachings of the prior art the novel diamines have surprisingly good reaction times to form polyurethanes with excellent physical properties. Furthermore, little or no mold release is required in RIM and other processes using the chain extenders of the invention.

REFERENCES:
patent: 2683730 (1954-07-01), Seeger et al.
patent: 3362979 (1968-01-01), Bentley
patent: 3428610 (1969-02-01), Klebert
patent: 4218543 (1980-08-01), Weber et al.
patent: 4314962 (1982-02-01), Wollensak et al.
patent: 4420570 (1983-12-01), Dominguez
Polyurethanes, Chemistry and Technology, Saunders & Frisch, Interscience Publishers, 1964, pp. 116-117 & 231-233.
Journal of Organic Chemistry, vol. 46, Beak et al., p. 2368, (1981).

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