Polyurethane-polyester hybrid resin system having improved stabi

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524589, 524248, 524249, 524259, 524260, 524340, 524347, 524349, 524351, 525 28, 525440, 525445, C08J 300, C08K 320, C08L 7500, C08F 2000

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058212965

ABSTRACT:
The present invention is drawn to a polyurethane-polyester hybrid resin system wherein the components of the system have improved shelf life stability. The resin system comprises an A-Side comprising a multifunctional isocyanate and a free radical initiator. The hybrid resin system also comprises a B-Side comprising a hydroxyl-terminated unsaturated polyester polyol, an ethylenically unsaturated monomer, a polyurethane catalyst, a polymerization inhibitor, and optionally a peroxide promoter, chain extender and filler. The B-Side polymerization inhibitor of the present invention comprises substituted hindered phenol-type compounds with ring substituents producing activated benzylic hydrogens, nitrophenols with or without benzylic-type substituents, naphthoquinones, stabilized radical compounds, and mixtures thereof.

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