Polyurethane elastomers exhibiting improved demold, green streng

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heterocyclic reactant containing as ring atoms oxygen,...

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25218227, 568624, C07C 4311

Patent

active

057928290

ABSTRACT:
Polyurethane elastomers exhibiting improved green strength while maintaining short demold times are prepared from ultra-low unsaturation polyoxypropylene polyols containing up to 20 weight percent internal random oxyethylene moieties. The elastomers adsorb less than 10 weight percent water at 0.degree. C. The internal polyoxyethylene moiety-containing polyoxypropylene polyols may be used to prepare ultra-low unsaturation polyoxyethylene capped polyols which are haze-free and which may be used to prepare haze-free 4,4'-MDI prepolymers. Multidisperse blends of monodisperse internal oxyethylene moiety-containing polyoxypropylene polyols of ultra-low unsaturation provide yet further improvements in elastomer processing.

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C.P. Smith et al., "Thermoplastic Polyurethane Elastomers Made From High Molecular Weight Poly-L.TM. Polyols", Polyurethane World Congress 1991, Sep. 24-26, 1991, pp. 313-318.

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