Polysubstituted fullerenes and their preparation

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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560 89, 564308, 568719, 568930, C07C 3923, C07C23540

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active

052947327

ABSTRACT:
The present invention is directed to polysubstituted fullerene moieties having a plurality of substituents thereon wherein the substituents are selected from the group consisting of hydroxy in combination with hydroxy, amino, oxide, nitro, organocarboxy, amide and mixtures thereof.

REFERENCES:
J. Am. Chem. Soc. (1991) 113, 9384-9387; Olah et al.
H. Selig, et al., Fluorinated Fullerenes, 1991, 113, 5475-5476, J. Am. Chem. Soc.
Christophe Jehoulet, et al., Electrochemical Reduction and Oxidation of C.sub.60 Films, 1991, 113, 5456-5457, J. Am. Chem. Soc.
Joe M. Wood et al., Oxygen and Methylene Adducts of C.sub.60 and C.sub.70, 1991, 113, 5907-5908, J. Am. Chem. Soc.
Joel M. Hawkins, et al., Organic Chemisry of C.sub.60 (Buckminsterfullerene): Chromatography and Osmylation, 1990, 55, 6250-6252, J. Org. Chem.
Stephen G. Kukolich, et al., EPR Spectra of C.sub.60 Anion and Cation Radicals, Aug. 2, 1991, vol. 182, No. 3.4, pp. 263-265, Chemical Physics Letters.
Paul J. Fagan, et al., The Chemical Nature of Buckminsterfullerene (C.sub.60) and the Characterization of a Platinum Derivative, May 24, 1991, vol. 252, pp. 1160-1161, Science.
Roger Taylor, A Valence Bond Approach to Explaining Fullerene Stabilities, 1991, vol. 32, No. 30, pp. 3731-3734, Tetrahedron Letters.
George A. Olah, et al., Chlorination and Bromination of Fullerens. Nucleophilic Methoxylation of Polychlorofullerenes and Their Alumin Trichloride Catalyzed Friedel-Crafts Reaction with Aromatics to Polyarylfullerenes, 1991, 113, 9385-9387, J. Am. Chem. Soc.
George A. Olah, et al., Polyarenefullerenes, C.sub.60 (H-Ar).sub.n Obtained by Acid-Catalyzed Fullerenation of Aromatics, 1991, 113, 9387-9388, J. Am. Chem. Soc.
Wudl et al., Fullerenes Synthesis, Properties, and Chemistry of Large Carbon Clusters, A.C.S. Symposium Series 481, Ch. 11, pp. 161-175, 1992.
Chiang, et al., Materials Research Society Symposium Proceedings, Dec. 2-6, 1991, vol. 247: Electrical, Optical and Magnetic Properties of Organic Solid State Materials, 1992, Materials Research Society, Pittsburgh, Pa., U.S.A.
L. S. Sunderlin, et al., Gas-Phase Reactivity of Fullerene Anions, 1991, 113, 5489-5490, J. Am. Chem. Soc.

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