Polystyrene immobilized rhodium complex catalyst for the hydrofo

Details Polystyrene immobilized rhodium complex catalyst for the hydrofo Polystyrene immobilized rhodium complex catalyst for the hydrofo

1990-09-24

1992-03-03

Garvin, Patrick P.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

502152, 502159, 502161, 502167, B01J 3128

Patent

active

050932977

ABSTRACT:
Olefins are hydroformylated to aldehyde in the presence of polymer immobilized rhodium catalysts. These catalysts are suit for the hydroformylation of olefins in the organic solvent or in the aqueous phase.

REFERENCES:
patent: 4323698 (1982-04-01), Haag et al.
Grubbs et al., J. Am. Chem. Soc. 93, 3062-3063, (1971).
Pittman, C. U., Smith, L. R., Hanes, R. M., Journal Of The American Chemical Society /97:7/ Apr. 2, 1975 entitled "Catalytic Reactions Using Polymer-Bound vs. Homogeneous Complexes of Nickel, Rhodium and Ruthenium", pp. 1742-1748.
Batchelder, R. F., Gates, B. C., Kuijpers, F. P. J., 6th International Congress On Catalysis, (1976), pp. 499-508 entitled "Multifunctional Catalysis by Matrix-bound Rhodium (I) Complex and Amine Groups: Application to the Aldox Process".
De Munck, N. A., Verbruggen, M. W., Scholten, J. J. F., Journal Of Molecular Catalysis, 10 (1981), pp. 313-330 entitled "Gas Phase Hydroformylation of Propylene With Porous Resin Anchored Rhodium Complexes Part I. Methods of Catalyst Preparation and Characterization".

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