Polysiloxazanes, silicon oxynitride fibers and processes for pro

Chemistry of inorganic compounds – Silicon or compound thereof – Oxygen containing

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423324, C01B 3320, C01B 1514

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active

049650580

ABSTRACT:
Novel polysiloxazanes comprising --SiH.sub.2).sub.n NH-- and --SiH.sub.2).sub.m O-- as the main repeating units are provided. The polysiloxazanes are produced by reacting a dihalosilane or an adduct thereof with a Lewis base, with ammonia and water vapor or oxygen. From the polysiloxazane, novel silicon oxynitride shapes can be produced and the silicon oxynitride shapes are essentially composed of silicon, nitride (5 mols % or more) and oxygen (5 mol % or more).

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Okamura et al., The Synthesis Oxynitride Fibers by Nitridation of Polycarbosilane, Chemistry Letters, pp. 2059-2060, 1984, The Chemical Society of Japan.

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