Polysilazanes and related compositions, processes and uses

Compositions: ceramic – Ceramic compositions – Refractory

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501 95, 501 96, 528 10, 528 28, 264 65, 423353, C04B 3558

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active

050554310

ABSTRACT:
Silazanes and related compounds are prepared by providing a precursor containing one or more cyclic silazane units, causing polymerization to occur in the presence of a transition metal catalyst to form a polysilazane product. Further products may result from additional reaction. The novel compounds may be pyrolyzed to yield ceramic materials such as silicon nitride, silicon carbide and mixtures thereof. In a preferred embodiment, substantially pure silicon nitride and articles prepared therefrom are provided. Fibers, coatings, binders and the like may be prepared from the novel materials.

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