Polysaccharides containing aromatic aldehydes and their derivati

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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536 30, 536 43, 536 45, 536 46, 536 50, 536 52, 536 56, 536 84, C08B 1116, C08B 3018, C08B 3114, C08B 3304, C08B 3504, C08B 3700

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050119184

ABSTRACT:
A polysaccharide derivative having the structure Sacch--O--Z--Ar--CH.dbd.N--Y or ##STR1## where Sacch--O-- represents a polysaccharide molecule; Z is --(CH.sub.2).sub.n -- or ##STR2## Ar is a divalent aromatic group; Y is (a) a monovalent group derived from a water-soluble substituted or unsubstituted aromatic compound containing only one free primary amine group, or (b) a monovalent group derived from a water-soluble substituted or unsubstituted aliphatic or cycloaliphatic compound containing only one primary amine group, or (c) a multivalent group derived from a water-soluble protein containing more than one primary amine group; n is one or greater; and m is zero or greater, is prepared by first modifying the polysaccharide with a reagent to introduce free aromatic aldehyde groups and then reacting with a suitable amine-containing reagent. The siloxane-containing starch derivaties are useful in glass forming size compositions.

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patent: 4663448 (1987-05-01), Chiu
patent: 4675394 (1987-06-01), Solarek et al.
patent: 4703116 (1987-10-01), Solarek et al.
patent: 4719272 (1988-01-01), Tsai et al.
patent: 4741804 (1988-05-01), Solarek et al.
patent: 4788280 (1988-11-01), Billmers et al.
patent: 4801699 (1989-01-01), Jobe et al.
patent: 4857505 (1989-08-01), Arendt
patent: 4866151 (1989-09-01), Tsai et al.
Chemical Abstracts, vol. 98, 200152m, 1983, Japanese Patent 57202362, dated 12/82.

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