Polyphotoinitiators and compositions thereof

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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20415922, 20415924, 528 15, 528 24, 528 25, 528 26, 528 29, 528 33, 528 37, C08F 246

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active

044773269

ABSTRACT:
Polysiloxane polymers with photoinitiating functionality. The polymers may be obtained by reacting .alpha.-allylbenzoin ethers with a siloxane or polysiloxane containing a plurality of silicon hydride groups. Alternatively, the allylbenzoin ethers may be reacted with a hydrolyzable hydrosilane and further reacted with other hydrolyzable organosilanes or siloxanes to form the polysiloxane with pendant photoinitiating benzoin ether groups. The other hydrolyzable silanes or siloxanes may include photocurable groups to yield self curing polymers. In the same manner, photoinitiating siloxane polymers of the first method may be further polymerized to yield self curing products. The photoinitiating polymers may also be combined with ethylenically unsaturated monomers or other silicones with photocurable groups to yield photocurable compositions.

REFERENCES:
patent: 4273907 (1981-06-01), Takamizawa et al.
patent: 4391963 (1983-07-01), Shirahata
Chemical Abstracts 97: 23997x, 1982.

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