Polyphosphazene semipermeable membranes

Liquid purification or separation – Filter – Material

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21050021, C02F 144, B01D 1300

Patent

active

047494891

ABSTRACT:
A semipermeable, inorganic membrane is disclosed; the membrane is prepared from a phosphazene polymer and, by the selective substitution of the constituent groups bound to the phosphorous in the polymer structure, the selective passage of fluid from a feedstream can be controlled. Resistance to high temperatures and harsh chemical environments is observed in the use of the phosphazene polymers as semipermeable membranes.

REFERENCES:
patent: 4710204 (1987-12-01), Kraus
Allock, H. R. "Phosphorus-Nitrogen Compounds-cyclic, Linear and High Polymeric Systems", Academic Press, N.Y., 1972, Chap. 16.
McAtee, R. E. et al., "The Synthesis and Casting of Phosphazene . . . " Abs. From Workshop of Phos. Chem., U.S. Naval Acad. Nov. 6-7, 1985, 1 page.
Allen, C. A. et al., "Polyphosphazene Membrane Research . . . ", Abs. From Workshop of Phos. Chem., U.S. Naval Acad., Nov. 6-7, 1985, 1 page.
Allcock, H. R. et al., "PHosphonitrilic Compounds . . . ", Inorganic Chemistry, 5, No. 10, Oct. 1966, p. 1709-1715.
Singler, R. E., et al., "Synthesis and Characterization of Polyacryloxyphozenes", J. of Poly. Science: Polymer Chem. Ed., vol. 12, 1974, p. 433-444.
Allcock, H. R. et al., "Phosphonitrile Compounds . . . ", Inorganic Chemistry, vol. 11, No. 11, 1972, p. 2584-2590.
Allcock, H. R. "Phosphazene High Polymers", Chemistry in Britain, vol. 10 (4), 1974, p. 118-121.
Allcock, H. R. "Poly(Organophospaazenes) . . . ", Angew. Chem. Int. Ep. Engl. vol. 16, 1977, p. 147-156.
Allock, H. R. "Inorganic Macromolecules", C+EN, vol. 63, No. 11, Mar. 18, 1985, p. 22-34.
Allen, C. A. et al. "Inorganic Membrane Techology", Abs., Northwest Am. Chem. Soc. Jun. 19-21, 1985, No. 139.
Allen, C. A. et al., "Inorganic Membrane Technology", Abs. From The Symp. On Sep. Science and Tech. For Engy. Appl., Oct. 20-24, 1985, p. 49.

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