Polyphosphazene compounds and method of preparation

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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528399, C08G 7300

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active

044120532

ABSTRACT:
Shown are fully alkylated/arylated polyphosphazenes having side units bonded to the phosphorus backbone by direct carbon-phosphorus bonds. A method of preparing the polyphosphazenes includes the thermal decomposition of and elimination of silanes from suitably constructed N-silylphosphinimines.

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patent: 4258171 (1981-03-01), Hergenrother et al.
Allcock "Ring-Ring and Ring-Chain Equilibration of Dimethylphosphazenes", Inorganic Chemistry, vol. 16, No. 1, 1977.
Allcock, "Synthesis of Alkyl and Aryl Phosphazene High Polymers", Journal of the American Chemical Society, Aug. 31, 1977, pp. 6095-6096.
Neilson, "Silicon-Nitrogen-Phosphorus Compounds as Phosphazene Precursors", 178th ACS Meeting, Washington, DC Sep. 1979.

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