Compositions – Fire retarding – For solid synthetic polymer and reactants thereof
Reexamination Certificate
2001-11-28
2003-06-10
Buttner, David J. (Department: 1712)
Compositions
Fire retarding
For solid synthetic polymer and reactants thereof
C524S096000, C524S097000, C528S167000, C528S168000, C544S084000, C544S157000
Reexamination Certificate
active
06576161
ABSTRACT:
FIELD OF THE INVENTION
The invention relates to polyphosphate ester morpholides, compositions comprising mixtures thereof, and flame retardant thermoplastic resin compositions containing the same.
BACKGROUND OF THE INVENTION
For a long time it has been a main target in conducting research and development of resins to find a technique to improve flame retardancy of thermoplastic resins. So far, a variety of compounds have been proposed as a flame retardant agent. Flame retardant agents, which are generally used in the thermoplastic resin field, include a flame retardant agent based on a halogenic compound, particularly, a bromic compound, and a phosphorus flame retardant agent based on phosphoric acid ester. Such flame retardant agents are used with a fluorinated polyolefin as a anti-drip agent or an antimony compound as a flame retardation assistant.
However, as concerns about the environmental issue increase, there is a trend to restrain the use of the halogen based flame retardant agent. Therefore, the phosphorus flame retardant agent, which is free of any halogen compound, is preferred to the flame retardant agent. Such a phosphorus flame retardant agent includes monomeric aromatic phosphoric acid ester compounds such as triphenyl phosphate, tricresyl phosphate and the like. The flame retardant agents comprising the monomeric aromatic phosphoric acid ester compounds can provide excellent flame retardancy and desired mechanical properties. However, such a flame retardant agent tends to migrate to the surface of a molded article during a molding process, thereby causing a juicing phenomenon. Furthermore, there is a disadvantage in that heat resistance of the resultant resin composition is remarkably reduced.
Accordingly, in order to overcome the above-mentioned problems, Japanese Patent Laid-Open Publication Nos. Sho59-24736, Sho59-45351, and Sho59-202240 disclose the use of an oligomeric condensed phosphoric acid ester compound as a flame retardant agent for thermoplastic resins. The disclosed flame retardant agents have advantages in that they involve a reduced juicing phenomenon while relatively improving the heat resistance of the resultant resin when they are applied to thermoplastic resins. However, they exhibits a reduced flame retardancy, as compared to that obtained when the same amount of the flame retardant agent based on the monomeric phosphoric acid ester is used. Therefore, it is needed to add the flame retardant agent in an increased amount so as to achieve an equal level of flame retardancy.
Phosphoramide flame retardants are disclosed in Japanese Kokai Publication No. 2000-154277 including phenyl morpholide monophosphate compounds. These compounds are disclosed as flame retardants suitable for use with various synthetic resins. The synthesis of diphenyl morpholide monophosphate and dimorpholide phenyl monophosphate is described. There is no disclosure of derivatives of the monophosphates or reacting the monophosphates with any other compounds.
SUMMARY OF THE INVENTION
The present invention relates to polyphosphate ester morpholides, compositions comprising mixtures thereof and thermoplastic resin compositions containing the polyphosphate ester morpholide composition as a flame retardant. The thermoplastic resin compositions according to the present invention have improved properties such as flame retardancy, mechanical properties, workability, impact strength, heat resistance and the like. The polyphosphate ester morpholides contain a functional group having a nitrogen atom and an oxygen atom have a great electron affinity to the conventional oligomeric phosphoric acid ester compound.
REFERENCES:
patent: 4062909 (1977-12-01), Morgan
patent: 59-45351 (1984-03-01), None
patent: 59-202240 (1984-11-01), None
patent: 2000-154277 (2000-06-01), None
Lim Jong-Cheol
Seo Kyung-Hoon
Yang Sam-Joo
Buttner David J.
Cheil Industries Inc.
Tungol Maria Parrish
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