Polyoxyalkylene ethers having hydroxyl and sulfonate groups and

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524839, 524591, C08G 1850, C08L 7508

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active

050011898

ABSTRACT:
Polyoxylalkylene ether with an average molecular weight of 400 to 10,000 with at least one terminal hydroxyl group and at least one lateral --SO.sub.3 X group (X=hydrogen, alkali metal or ammonium ion) is disclosed. The polyoxyalkylene ether is obtainable by the statistical or blockwise addition reaction of (a) .alpha.-alkylene oxides with 2 to 14 carbon atoms or mixtures thereof and (b) allyl and/or methallyl glycidyl ethers to monohydric to quadrihydric aliphatic alcohols with up to 8 carbon atoms, the ratio of component (a) to component (b) being selected so that at least one allyl ether group is linked to the average molecule, reacting the polymer by a known reaction with, based on the allyl ether groups, at least equimolar amounts of a compound of the formula HSO.sub.3 Y (Y=alkali or ammonium ion) and if necessary, exchanging the cation Y against a hydrogen ion also by a known procedure.
The compounds are suitable as polyol components for the preparation of stable, ionic, aqueous polyurethane dispersions with a high solids content.

REFERENCES:
patent: 3337615 (1967-08-01), Roberts
patent: 4056564 (1977-01-01), Wolf
patent: 4436672 (1984-03-01), Naylor
patent: 4594200 (1986-06-01), Penny
patent: 4612142 (1986-09-01), Piorr
patent: 4618457 (1986-10-01), Esselborn

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