Polyoxometallate catalysts and catalytic processes

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

Reexamination Certificate

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C562S400000, C568S399000, C502S208000, C502S150000, C585S467000

Reexamination Certificate

active

07019165

ABSTRACT:
An active and selective hydrocarbon partial oxidation catalyst comprises an activated partially-reduced polyoxometallate, preferably niobium polyoxomolybdate, that is prepared from a suitable polyoxoanion, which has been exchanged with a suitable cation and activated by heating to an activation effective temperature in the presence of a suitable reducing agent such as pyridinium. C3and C4hydrocarbons may be partially oxidized selectively to acrylic acid and maleic acid.

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