Polyols from epoxidized tallow trimethylolpropane and propylene

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2604106, 260 22EP, C09F 508, C11C 300

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041246098

ABSTRACT:
Polyols suitable for use in urethane foams are made by a three-stage process that is much less dependent on petroleum-based chemicals than are prior art methods and that eliminates washing unreacted reagents out of the product. Trimethylolpropane is first reacted under acid catalysts with epoxidized tallow, the reacted epoxidized tallow is then reacted under alkaline catalysis with trimethylolpropane, and the resilient product reacted with propylene oxide.

REFERENCES:
patent: 3399154 (1968-08-01), Bernstein et al.
patent: 3689532 (1972-09-01), Emmons et al.
Bilyk et al., AOCS 67th Annual Spring Meeting, Apr. 21-24, 1976, Session I, Report #46.
Bilyk et al., Journal of the American Oil Chemists' Society, vol. 52, pp. 289-292 (1975).

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