Earth boring – well treating – and oil field chemistry – Well treating – Contains enzyme or living micro-organism
Reexamination Certificate
2001-07-03
2003-09-09
Tucker, Philip (Department: 1712)
Earth boring, well treating, and oil field chemistry
Well treating
Contains enzyme or living micro-organism
C507S273000, C507S209000, C507S211000, C507S266000, C507S903000, C507S921000, C507S922000, C166S308400
Reexamination Certificate
active
06617285
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to gelled treatment fluids used during hydrocarbon recovery operations, and more particularly relates, in one embodiment, to methods of “breaking” or reducing the viscosity of treatment fluids containing gelling agents used during hydrocarbon recovery operations.
BACKGROUND OF THE INVENTION
Hydraulic fracturing is a method of using pump rate and hydraulic pressure to fracture or crack a subterranean formation. Once the crack or cracks are made, high permeability proppant, relative to the formation permeability, is pumped into the fracture to prop open the crack. When the applied pump rates and pressures are reduced or removed from the formation, the crack or fracture cannot close or heal completely because the high permeability proppant keeps the crack open. The propped crack or fracture provides a high permeability path connecting the producing wellbore to a larger formation area to enhance the production of hydrocarbons.
The development of suitable fracturing fluids is a complex art because the fluids must simultaneously meet a number of conditions. For example, they must be stable at high temperatures and/or high pump rates and shear rates that can cause the fluids to degrade and prematurely settle out the proppant before the fracturing operation is complete. Various fluids have been developed, but most commercially used fracturing fluids are aqueous based liquids that have either been gelled or foamed. When the fluids are gelled, typically a polymeric gelling agent, such as a solvatable polysaccharide is used. The thickened or gelled fluid helps keep the proppants within the fluid. Gelling can be accomplished or improved by the use of crosslinking agents or crosslinkers that promote crosslinking of the polymers together, thereby increasing the viscosity of the fluid.
The recovery of fracturing fluids may be accomplished by reducing the viscosity of the fluid to a low value so that it may flow naturally from the formation under the influence of formation fluids. Crosslinked gels generally require viscosity breakers to be injected to reduce the viscosity or “break” the gel. Enzymes, oxidizers, and acids are known polymer viscosity breakers. Enzymes are effective within a pH range, typically a 2.0 to 10.0 range, with increasing activity as the pH is lowered towards neutral from a pH of 10.0. Most conventional borate crosslinked fracturing fluids and breakers are designed from a fixed high crosslinked fluid pH value at ambient temperature and/or reservoir temperature. Optimizing the pH for a borate crosslinked gel is important to achieve proper crosslink stability and controlled enzyme breaker activity.
It would be desirable if a viscosity breaking system could be devised to break fracturing fluids gelled with borate crosslinked polymers by reducing the alkaline pH enough to both break the crosslinked gel viscosity and to increase the enzyme breaker activity, if enzymes are present.
SUMMARY OF THE INVENTION
Accordingly, it is an object of the present invention to provide a method for breaking the viscosity of aqueous treatment fluids gelled with borate crosslinked polymers used in hydrocarbon recovery operations.
It is another object of the present invention to provide a composition and method for breaking borate crosslinked aqueous fluids by lowering the pH of the alkaline fluid to make better use of an enzyme viscosity breaker.
Still another object of the invention is to provide a method and composition for breaking the viscosity of aqueous fluids gelled with borate crosslinked polymers that can provide better clean up of the crosslinked polymer.
In carrying out these and other objects of the invention, there is provided, in one form, a method for breaking viscosity of aqueous fluids gelled with borate crosslinked materials involving adding to an aqueous fluid gelled with at least one borate crosslinked polymer at least one polyol, in an amount effective to eventually reduce the pH of the fluid and remove at least a portion of borate ion from the crosslinked polymer; adding at least one enzyme to the aqueous fluid; and removing at least a portion of borate ion from the crosslinked polymer, reducing the pH of the fluid, and increasing the activity of the enzyme by reducing the pH.
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Baker Hughes Incorporated
Madan Mossman & Sriram P.C.
Tucker Philip
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