Polyolefin composition with improved impact properties

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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C525S192000, C525S193000, C525S197000, C525S212000, C525S240000, C525S261000, C525S331800, C525S333900, C525S349000, C525S351000, C525S352000

Reexamination Certificate

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06841620

ABSTRACT:
The present invention includes a composition comprising a coupled impact propylene copolymer. Preferably, the coupled impact propylene copolymer has an elastomeric phase that is present in an amount of at least 9 weight percent of the coupled propylene copolymer. Articles formed from the coupled propylene copolymer exhibit improved directionally balanced impact properties as compared with articles formed form comparable noncoupled impact propylene copolymers and also exhibit improved ductile-to-brittle transition temperatures compared with comparable noncoupled impact propylene copolymers. The invention also includes methods for making the coupled impact propylene copolymers using coupling agents, preferably, poly(sulfonyl azides). The invention further includes articles of manufacture that are made from the coupled impact propylene copolymer of the invention.

REFERENCES:
patent: 3058944 (1962-10-01), Breslow et al.
patent: 3203936 (1965-08-01), Breslow et al.
patent: 3203937 (1965-08-01), Breslow et al.
patent: 3282864 (1966-11-01), Bost et al.
patent: 3298975 (1967-01-01), Feild et al.
patent: 3336268 (1967-08-01), Cox
patent: 3341480 (1967-09-01), Feild
patent: 3377415 (1968-04-01), Oppenlander
patent: 3389198 (1968-06-01), Taber
patent: 3530108 (1970-09-01), Oppenlander
patent: 3645992 (1972-02-01), Elston
patent: 3687920 (1972-08-01), Johnson
patent: 3893989 (1975-07-01), Leicht et al.
patent: 3914342 (1975-10-01), Mitchell
patent: 3959425 (1976-05-01), Herrington
patent: 4003712 (1977-01-01), Miller
patent: 4076698 (1978-02-01), Anderson et al.
patent: 4113802 (1978-09-01), Matteoli et al.
patent: 4200556 (1980-04-01), Robinson et al.
patent: 4352892 (1982-10-01), Lohmar
patent: 4532189 (1985-07-01), Mueller
patent: 4579905 (1986-04-01), Krabbenhoft
patent: 4584347 (1986-04-01), Harpell et al.
patent: 4694025 (1987-09-01), Park
patent: 4714716 (1987-12-01), Park
patent: 4820471 (1989-04-01), van der Molen
patent: 4916198 (1990-04-01), Scheve et al.
patent: 5008204 (1991-04-01), Stehling
patent: 5037895 (1991-08-01), Marker et al.
patent: 5116881 (1992-05-01), Park et al.
patent: 5180751 (1993-01-01), Park et al.
patent: 5266643 (1993-11-01), Mustonen et al.
patent: 5272236 (1993-12-01), Lai et al.
patent: 5278272 (1994-01-01), Lai et al.
patent: 5284613 (1994-02-01), Ali et al.
patent: 5348795 (1994-09-01), Park
patent: 5358792 (1994-10-01), Mehta et al.
patent: 5373236 (1994-12-01), Tsui et al.
patent: 5414027 (1995-05-01), DeNicola, Jr. et al.
patent: 5491019 (1996-02-01), Kuo
patent: 5519785 (1996-05-01), Hara
patent: 5527573 (1996-06-01), Park et al.
patent: 5567742 (1996-10-01), Park
patent: 5605936 (1997-02-01), DeNicola, Jr. et al.
patent: 5616627 (1997-04-01), Sakurai et al.
patent: 5641848 (1997-06-01), Giacobbe et al.
patent: 5747594 (1998-05-01), deGroot et al.
patent: 5767033 (1998-06-01), Imuta et al.
patent: 5844045 (1998-12-01), Kolthammer et al.
patent: 5869575 (1999-02-01), Kolthammer et al.
patent: 5883151 (1999-03-01), Raetzsch et al.
patent: 5929129 (1999-07-01), Feichtinger
patent: 6054540 (2000-04-01), Chaudhary et al.
patent: 6103833 (2000-08-01), Hogt et al.
patent: 6143829 (2000-11-01), Babb et al.
patent: 6143854 (2000-11-01), Bamberger
patent: 6207754 (2001-03-01), Yu
patent: 6211302 (2001-04-01), Ho et al.
patent: 6284842 (2001-09-01), Ho et al.
patent: 6417242 (2002-07-01), Hughes et al.
patent: 6472473 (2002-10-01), Ansems et al.
patent: 6506848 (2003-01-01), Hoenig et al.
patent: 797 917 (1968-10-01), None
patent: 1 024 296 (1978-01-01), None
patent: 1 219 389 (1987-03-01), None
patent: 1 569 025 (1970-07-01), None
patent: 0 351 208 (1990-01-01), None
patent: 0 474 376 (1992-03-01), None
patent: 0 595 252 (1994-05-01), None
patent: 0 702 032 (1996-03-01), None
patent: 0 747 376 (1996-05-01), None
patent: 0 634 454 (1997-11-01), None
patent: 0 625 545 (1998-01-01), None
patent: 0 634 441 (1998-05-01), None
patent: 0 872 517 (1998-10-01), None
patent: 1 080 619 (1967-08-01), None
patent: 2 205 103 (1988-11-01), None
patent: 46-31756 (1971-09-01), None
patent: 50-133248 (1975-10-01), None
patent: 51-134762 (1976-11-01), None
patent: 9304486 (1993-03-01), None
patent: 9607681 (1996-03-01), None
patent: 9620247 (1996-07-01), None
patent: 9720888 (1997-06-01), None
patent: 9720889 (1997-06-01), None
patent: 9910415 (1999-03-01), None
patent: 9910424 (1999-03-01), None
patent: 9910426 (1999-03-01), None
patent: 0002960 (2000-01-01), None
patent: 0002961 (2000-01-01), None
patent: 0052091 (2000-09-01), None
patent: 0053669 (2000-09-01), None
patent: 0078858 (2000-12-01), None
patent: 0078861 (2000-12-01), None
R. A. Abramovitch, Polar Radicals in Aromatic Substitution,Intra-Science Chemistry Reports,pp. 211-218, 1969.
R. A. Abramovitch et al., “Reaction of Sulphonyl Azides with Unstrained Olefins”,J. Chem. Soc.,pp. 2169-2172, 1974.
R. A. Abramovitch et al., Intramolecular Insertion of Arylsulfonylnitrenes into Aliphatic Side Chains,J. Org. Chem.,vol. 42, No. 17, pp. 2920-2926, 1977.
R. A. Abramovitch et al., Pyrolysis of Phenylaikylsulphonyl Azides and 2-phenethyl Azidofomate. Selectivity of Sulphonylnitrenes And Constrast between Sulphonyl-and Carbonyl-nilrenes,J. Chem. Soc. Chem Commun.,pp. 1087-1088, 1981.
R. A. Abramovitch et al., “Reaction of Aromatic Sulfonyl Azides with Dienes”,J. Org. Chem.,vol. 46, pp. 330-335, 1981.
H. Radusch et al., “Chemical coupling of polystyrene and polybutadiene in melt mixtures by using an organic sulfonylazide”,Die Angewandte Makromolekulare Chemie,vol. 204, pp. 177-189, 1993.
N. Takashima et al., “The Processings of Crosslinked Plastics”,Kogaku Kogyo(Chemical Industry), pp. 378-383, 1969.
D. S. Breslow et al., “Thermal Reactions of Sulfonyl Azides”,Amer. Chem. Soc.,vol. 91, pp. 2273-2279, 1969.
*Derwent Chemical Abstract No. 1977-02552Y of JP 51-134762A.
*Derwent Chemical Abstract No. 1977-88691Y of JP 50-133248.
M. Xanthos, “Interfacial Agents of Multiphase Polymer systems: Recent Advances”,Polymer Engineering and Science,vol. 28, pp. 1392-1400, 1988.
K. A. Chaffin et al., “Semicrystalline Blends of Polyethylene and Isotactic Polypropylene: Improving Mechanical Performance by Enhancing the Interfacial Structure”,Journal of Polymer Science: Part B: Polymer Physics,vol. 38, pp. 108-121, 2000.
E. P. Moore,Polypropylene Handbook,pp. 15-45, 1996.
E.P. Moore,Polypropylene Handbook,p. 220, 1996.
E.P. Moore,Polypropylene Handbook,pp. 330-332, 1996.
Han and Shetty, “Studies on Multilayer Film Coextrusion III. The Rheology of Blown Film Coextension”,Polymer Engineering and Science,vol. 18, No. 3, pp. 187-199, 1978.
Inoue, “Selective Crosslinking in Polymer Blends. I. Novel Selective Crosslink Systems for Polypropylene/Unsaturated Elastomer Blends”,Journal of Applied Polymer Science,vol. 54. pp. 709-721, 1994.
Inoue, “Selective Crosslinking in Polymer Blends. II. Its Effect on Impact Strength and Other Mechanical Properties of Polyproplene/Unsaturated Elastomer Blends”,Journal of Applied Polymer Science,vol. 54, pp. 723-733, 1994.
Inoue and Suzuki, “Selective Crosslinking Reaction in Polymer Blends. III. The Effects of the Crosslinking of Dispersed EPDM Particles on the Impact Behavior of PP/EPDM Blends”,Journal of Applied Polymer Science,vol. 56, pp. 1113-1125, 1995.
U.S. Appl. No. 09/133,576 filed Aug. 13, 1998 (43324A), Craig Silvis et al., “In-Situ Rhelogy Modification of Polyolefins”.
U.S. Appl. No. 10/121,985 filed Apr. 12, 2002 (60329A), Li-Min Tau et al., “Composition and Films Thereof”.

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