Polymers prepared from imide containing dianhydrides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 302, 260 324, 260306R, 260 306SB, 260 326N, 260 328SB, 260 465E, 260 65, 260 78TF, 260 78A, 260326C, 428458, 428474, C08G 7310

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039547108

ABSTRACT:
Thermoplastic imide polymers prepared from a dianhydride monomer containing imide linkages and at least two cyclic anhydride groups and an aromatic diamine such as 4,4'-diaminodiphenyl ether. Comonomers such as 3,4:3', 4'-benzophenonecarboxylic dianhydride may be added. Preferably said dianhydride monomer containing imide linkages is made by reacting 4-aminophthalic acid with a dianhydride containing at least two cyclic anhydride groups, preferably in the ratio of about 2:1. Preferably said imide polymer is made by first forming a solution containing the diamine and adding the dianhydride monomer containing imide linkages while the temperature of the solution is maintained between 50.degree. and 120.degree.C. and most preferably at 110.degree.C.

REFERENCES:
patent: 3485796 (1969-12-01), Naselow
patent: 3505295 (1970-04-01), Grunsteidl et al.
patent: 3511807 (1970-05-01), Lovejoy
patent: 3716519 (1973-02-01), Yoda et al.
patent: 3736290 (1973-05-01), Fessler

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