Polymers of ferrocene

Details Polymers of ferrocene Polymers of ferrocene

1981-11-09

1985-08-20

Sneed, Helen M. S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 19, 556 20, 556 30, C07F 966, C07F 990, C07F 1702

Patent

active

045365890

ABSTRACT:
Novel linear polymers of ferrocene are prepared by the reaction of 1,1'-dilithioferrocene with controlled amounts of a dihaloorganylphosphine, arsine or stibine. The polymers form stable complexes with Group VIII metals which are useful as recoverable hydroformylation catalysts.

REFERENCES:
patent: 3238185 (1966-03-01), Neuse
patent: 3418350 (1968-12-01), Sollott et al.
patent: 4138420 (1979-02-01), Unruh et al.
Seyferth et al., J. Organometallic Chem. 185 C.sub.1 -C.sub.5 (1980).
Sullivan et al., Organic Prep. and Proc. 2 (3), 159-159 (1970).
Bishop et al., J. Organometallic Chem. 27, 241-249 (1971).
Neuse et al., J. Macromol. Sci. (Chem.) A1 (3), 371-386 (1967).
Pittman, J. of Polymer Science PtA-1V5, 2927-2937 (1967).
Withers et al., Organometallics 1, 1283 (1983).

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