Polymers containing amide moieties and a process for their prepa

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

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528 44, 528408, 528361, 528172, C08G 1860

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active

049962817

ABSTRACT:
A polymer comprising a backbone portion containing at least one amide moiety and a plurality of imidazole, benzimidazole, benzoxazole, or benzothiazole moieties is prepared by contacting a polyisocyanate with a compound containing at least two end moieties selected from the following: imidazole, benzimidazole, benzoxazole, or benzothiazole, under reaction conditions sufficient to form the corresponding polymer containing amide moieties are disclosed. The process of the invention is suitable for the preparation of thermoset polymers which are advantageously free of surface defects, since a solvent is not required and no volatiles are evolved during the curing process. Urethane and/or urea polymers comprising a backbone portion containing at least one urea or urethane moiety, at least one amide moiety, and a plurality of imidazole, benzimidazole, benzoxazole, or benzothiazole moieties are also disclosed.

REFERENCES:
patent: 3625992 (1971-12-01), Ando
patent: 4369302 (1983-01-01), Ikegucyi et al.
patent: 4391957 (1983-07-01), Becker
patent: 4472567 (1984-09-01), Zecher et al.
patent: 4785070 (1988-11-01), Rasmussen et al.
Papadopoulos, Reactions of Imidazoles with Isocyanates at Elevated Temperature J. Org. Chem., vol. 42, No. 24, 1977, 3925-3929.
Kikugawa, A Facile N-Alkylation of Imidazoles and Benzimidazoles, Synthesis, 124-125.
Chemical Abstract 105089t, Synthesis of 5,5'(or 6,6')-Bibenzimidazole from Non-Carcinogenic Compounds.

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