Polymers containing alternating silsesquioxane and bridging grou

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heavy metal or aluminum reactant having at least one...

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528 37, 528 38, 528 40, 528 25, 556450, 556455, 556460, C08G 7704

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055895620

ABSTRACT:
A synthesis process for polysilsesquioxanes which produces a high yield, tractable copolymer of perfectly alternating silsesquioxane and bridging group segments is provided. A difunctional silsesquioxane monomer of the formula Si.sub.8 R.sub.8 O.sub.11 (OA).sub.2 or Si.sub.7 R.sub.7 O.sub.9 (OSiR.sup.4 R.sup.5 R.sup.6) (OA).sub.2 is reacted with a difunctional compound of the formula X-M-X which forms a bridging group for a time sufficient to condense the difunctional silsesquioxane monomers and bridging groups into a linear polymer containing alternating silsesquioxane and bridging group segments. The resulting linear copolymer is essentially free of impurities and has controllable properties through the proper selection of the monomeric starting materials.

REFERENCES:
patent: 3294737 (1966-12-01), Krantz
patent: 4349609 (1982-09-01), Takeda et al.
patent: 4513132 (1985-04-01), Shoji et al.
patent: 4745169 (1988-05-01), Sugiyama et al.
patent: 4871616 (1989-10-01), Kimura et al.
patent: 5039771 (1991-08-01), Morimoto et al.
patent: 5043789 (1991-08-01), Linde et al.
patent: 5047472 (1991-09-01), Weidner et al.
patent: 5247043 (1993-09-01), Nakashima
patent: 5412053 (1995-05-01), Lichtenhan et al.
Lichtenhan et al., "Silsesquioxane-Siloxane Copolymers from Polyhedial Silsesquioxanes" Macromolecules, 1993, 26 No. 8.
Laine et al, Chem. Mat.,(1990), V. 2:464-472.
Rahn et al, Mat. Res. Soc. Symp. Proc.(1990), V. 171:31-37.
Feher et al, "Silsesquioxanes as Models for Silica Surfaces," J. Am. Chem. Soc., 1989, 111, pp. 1741-1748.
Lichtenhan et al, "Silsesquioxane-Siloxane Copolymers from Polyhedral Silsesquioxanes," Macromolecules, 1993, 26 No. 8.
"Ladder and Spiro Polymers," Concise Encyclopedia of Polymer Sci. & Eng., 1990, pp. 516-521.
Feher et al, "Enhanced Silylation Reactivity of a Model for Silica Surfaces," J. Am. Chem. Soc., 1990, 112, pp. 1931-1936.
Taylor et al, "The Preparation, Characteristics, and Use of Siloxanes as Precursors to Silicon Carbide," Polymer Preprints, vol. 32, 1991, pp. 586-587.

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