Polymerization with initiator and quaternary ammonium salt

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526227, 526230, 526316, 5263285, 526332, C08F 434, C08F21636, C08F22010, C08F21612

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053449029

ABSTRACT:
An improved polymerization process wherein starting material such as monomer, a mixture of monomers, a partially polymerized product, or a mixture of fully polymerized product and monomer or monomer mixture is reacted with an initiator such as an organic peroxide, hydroperoxide or perester and a quaternary ammonium salt under polymerization conditions wherein polymerization or further polymerization of the starting material is initiated. The initiator and quaternary ammonium salt are miscible with the polymerization mixture in the absence of solvent. An improved polymerization process is also provided wherein a crosslinked polymer structure is formed from an unsaturated polymer in a polymerizable monomer.

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