Polymerization processes for broadened molecular weight...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S090000, C526S351000

Reexamination Certificate

active

07939610

ABSTRACT:
Provided are methods of producing polymers with broadened molecular weight and/or composition distribution in a continuous homogeneous polymerization system utilizing reactor temperature gradients, reactor polymer concentration gradients, monomer concentration gradients, catalyst concentration gradients, and combinations thereof in the polymerization reactor. Such methods are particularly suitable when utilizing metallocene catalysts and other single-site catalysts, which generally produce polymers with narrow molecular weight and composition distribution.

REFERENCES:
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patent: 5648438 (1997-07-01), Henry et al.
patent: 6727096 (2004-04-01), Wang et al.
patent: 2006/0270884 (2006-11-01), Beech et al.
patent: 2008/0081878 (2008-04-01), Jiang et al.
patent: 2008/0090974 (2008-04-01), Brant et al.

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