Polymerization process using zinc halide initiators

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C423S462000, C423S472000, C502S157000, C502S226000, C502S343000, C526S170000, C526S183000, C526S237000, C526S335000, C526S339000, C526S340200, C528S009000

Reexamination Certificate

active

07851577

ABSTRACT:
A cationic polymerization process for isoolefins using a zinc halide initiator. The zinc halide initiator is added to a solution of the isoolefin in a suitable solvent, preferably a halocarbon solvent. Polymerization reactions are normally conducted at temperatures high enough to allow the zinc halide initiator to dissolve in the solution. An alkyl halide activator may optionally be used and is preferably added to the solution prior to the zinc halide initiator. A multiolefin may optionally be present in the solution. The process is particularly useful in the formation of isoolefin homopolymers and co-polymers of isoolefins and multiolefins, such as butyl rubber.

REFERENCES:
patent: 2356128 (1944-08-01), Thomas et al.
patent: 3965078 (1976-06-01), Priola et al.
patent: 5703182 (1997-12-01), Langstein et al.
patent: 7041760 (2006-05-01), Bochmann et al.
patent: 2002/0132904 (2002-09-01), Langstein et al.
patent: 2005/0070680 (2005-03-01), Bochmann et al.
patent: 2441079 (2005-03-01), None
patent: 198 36 663 (2000-02-01), None
patent: 0 920 909 (1999-06-01), None
patent: 1 111 004 (2001-06-01), None
patent: 1 236 767 (2002-09-01), None
patent: 1 516 883 (2005-03-01), None
patent: 95/29940 (1995-11-01), None
patent: 99/09036 (1999-02-01), None
patent: 00/04061 (2000-01-01), None
Garratt et al., “Arylzinc Complexes as New Initiator Systems for the Production of Isobutene Copolymers with High Isoprene Content”, Mar. 15, 2004, Angew. Chem. Int.l Ed., 43(16), 2166-2169.
Guerrero et al., “Synthesis and Crystal Structure of Ethyl Zinc Chloride”, Feb. 7, 2006, Organometallics, 25(6), 1525-1527.
Guerroro, A., Kulbaba, K., and Bochmann, M., “Alkyl Zinc Chlorides as New Initiators for the Polymerization and Copolymerization of Isobutene”. Macromol. Chem. Phys. 2008, 209, 1714-1720.
Guerroro, A., Kulbaba, K., and Bochmann, M., “‘Highly Reactive’ Poly(isobutene)s via Room Temperature Polymerization with a New Zinc-Based Initiator System”. Macromolecules 2007, 40, 4124-4126.
Ullmanns Encyclopedia of Industrial Chemistry, vol. A 23 1993, pp. 288-295, Elvers et al “Rubber, 3. Synthetic”.
Song, X.; Thornton-Pett, M.; Bochmann, M.; Organometallics 1998, 17, pp. 1004-1006 “Synthesis, Structure, and Reactivity of (C5H4SiMe3)2Y{μ-FC6F4)(μ-Me)B(C6F5)2}: Tight Ion Pairing in a Cationic Lanthanide Complex”}.
Carr, A.G.; Dawson, D.M.; Bochmann, M.; M. Macromol. Rapid Commun. 1998, 19, 205-207 “The [Zr(N{SiMe3}2)3]+cation as a novel initiator for carbocationic isobutene homo- and isobutene/isoprene co-polymerisations”.
Chem. Eur. J. 2004, 10, pp. 6323-6332; Mario Vierle et al; “Solvent-Ligated Manganese(II) Complexes for the Homopolymerization of Isobutene and the Copolymerization of Isobutene and Isoprene”.
Morton, Maurice; “Rubber Technology” Third Edition, Chapter 10 (Van Nostrand Reinhold Company@ 1987) pp. 297-300.
Encyclopedia of Polymer Science and Engineering, vol. 4, S. 66 et seq. (Compounding) John Wiley & Sons.
Encyclopedia of Polymer Science and Engineering, vol. 17, S. 666 et seq (Vulcanization) John Wiley & Sons.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Polymerization process using zinc halide initiators does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Polymerization process using zinc halide initiators, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Polymerization process using zinc halide initiators will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4232303

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.