Polymerization process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Removing and recycling removed material from an ongoing...

Reexamination Certificate

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C526S064000, C526S065000, C526S905000, C422S132000

Reexamination Certificate

active

07666957

ABSTRACT:
A process for the polymerisation of ethylene and optionally at least one C3-20alpha olefin comonomer in the slurry or solution phase in a reactor having a polymer outlet stream, a procatalyst or catalyst feed stream and a hydrogen feed stream, said polymerisation being effected in the presence of a metallocene catalyst, a diluent and hydrogen, wherein said diluent is recycled from said outlet stream to said hydrogen feed stream, said procatalyst or catalyst feed stream is free of hydrogen, said hydrogen feed stream is free of procatalyst or catalyst and said procatalyst or catalyst feed stream does not comprise recycled diluent.

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patent: 2005/0234203 (2005-10-01), McGrath
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patent: WO 00/34341 (2000-06-01), None
patent: WO 00/53306 (2000-11-01), None
Kaminsky et al, Hydrogen transfer reactions of supported metallocene catalysts, J. of Molecular Catalysis A: Chemical 128 (1998) 191-200.

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