Polymerization process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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Details

C428S098000, C428S220000, C428S339000, C526S171000, C526S172000

Reexamination Certificate

active

06936674

ABSTRACT:
A process for producing a poly-olefin is disclosed, which comprises contacting at least one 1-olefin under polymerisation conditions with a polymerisation catalyst or catalyst system comprising (1) a compound having the Formula (I) wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III], Ru[IV], V[II], V[III], V[IV], or V[V], Ti[II], Ti[III] or Ti[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6and R7are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R1-R7are hydrocarbyl, substited hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and optionally (2) an activating quantity of an activator compound comprising a Lewis acid capable of activating the catalyst for olefin polymerisation; and then subjecting the resulting polyolefin to crosslinking conditions. The polymer produced can be formed into shaped articles or films with desirable physical properties

REFERENCES:
patent: 6274684 (2001-08-01), Loveday et al.
patent: 6368545 (2002-04-01), Bailey et al.
patent: 0 319 258 (1989-06-01), None
patent: WO98/27124 (1998-06-01), None
patent: WO99/12981 (1999-03-01), None
patent: WO99/46308 (1999-09-01), None

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