Polymerization of olefins with an improved catalyst system using

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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502127, 526351, C08F 4649

Patent

active

050667386

ABSTRACT:
The present invention provides a catalyst system that exhibits unprecedented catalyst efficiencies and control of desired properties in the polymer product. The catalyst system includes a new generation titanium catalyst in combination with an electron donor described by the formula: ##STR1## wherein R.sub.1 is bulky, basic alkyl or cycloalkyl group containing at least one secondary or tertiary carbon atom; R.sub.2 and R.sub.3 are alkyl or aryl groups; and R.sub.4 is an alkyl group with a primary carbon atom attached to the silicon atom. The system has a catalyst efficiency of at least about 30 kg/g-cat.2h as the Al/Si mole ratio varies from 20-200 in the system. The system easily achieves efficiencies over 60 kg/g-cat.2h. The system also exhibits good control over the xylene solubles, melt flow and molecular weight distribution of the polymer product.

REFERENCES:
patent: 4295991 (1981-10-01), Wristers
patent: 4816433 (1989-03-01), Terano et al.

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