Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Removing and recycling removed material from an ongoing...
Patent
1990-02-22
1993-01-05
Smith, Edward J.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Removing and recycling removed material from an ongoing...
525268, 526119, 526125, 526351, 526904, C08F 4651, C08F 4654, C08F 1000
Patent
active
051771624
ABSTRACT:
The present invention relates to an improvement of the known Ziegler catalyst which comprises a combination of a titanium-containing component and an organoaluminum component, and the present invention is characterized by a specific titanium-containing component. Namely, this titanium-containing component is obtained by contacting a known titanium-containing component of the Ziegler type catalyst which comprises Ti, Mg and a halogen, with an alkoxyalkylsilane compound which is characterized in that at least one of the alkyl groups has a branched structure. This catalyst does not require a so-called external electron donor, and no reduction of the polymerization velocity caused by the use of the electron donor is entailed. When this catalyst is used, a propylene/ethylene block copolymer in which the molecular weight of the propylene/ethylene copolymer portion and/or the polyethylene portion is increased, that is, the rigidity and impact strength are increased, can be prepared.
REFERENCES:
patent: 4387198 (1983-06-01), Sato et al.
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patent: 4442276 (1984-04-01), Kashiwa et al.
patent: 4547552 (1985-10-01), Toyota et al.
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Chemical Abstracts, vol. 94, No. 4, Jan. 1981, p. 20, Abstract No. 16366a, Columbus, OH, US & JP-A-80 108 406 (Chisso Corp) 20-08-1980.
Fujita Takashi
Matsuura Mitsuyuki
Mitsubishi Petrochemical Company Limited
Smith Edward J.
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