Polymerization of olefins

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Removing and recycling removed material from an ongoing...

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525268, 526119, 526125, 526351, 526904, C08F 4651, C08F 4654, C08F 1000

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051771624

ABSTRACT:
The present invention relates to an improvement of the known Ziegler catalyst which comprises a combination of a titanium-containing component and an organoaluminum component, and the present invention is characterized by a specific titanium-containing component. Namely, this titanium-containing component is obtained by contacting a known titanium-containing component of the Ziegler type catalyst which comprises Ti, Mg and a halogen, with an alkoxyalkylsilane compound which is characterized in that at least one of the alkyl groups has a branched structure. This catalyst does not require a so-called external electron donor, and no reduction of the polymerization velocity caused by the use of the electron donor is entailed. When this catalyst is used, a propylene/ethylene block copolymer in which the molecular weight of the propylene/ethylene copolymer portion and/or the polyethylene portion is increased, that is, the rigidity and impact strength are increased, can be prepared.

REFERENCES:
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patent: 4422956 (1983-12-01), Arzoumanidis et al.
patent: 4442224 (1984-04-01), Takitani et al.
patent: 4442276 (1984-04-01), Kashiwa et al.
patent: 4547552 (1985-10-01), Toyota et al.
patent: 4701505 (1987-10-01), Fujii et al.
Chemical Abstracts, vol. 94, No. 4, Jan. 1981, p. 20, Abstract No. 16366a, Columbus, OH, US & JP-A-80 108 406 (Chisso Corp) 20-08-1980.

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