Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From fluorine-containing reactant
Patent
1997-09-30
1998-10-06
Gulakowski, Randy
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From fluorine-containing reactant
528408, 528421, C08G 6522, C08G 5968
Patent
active
058177469
ABSTRACT:
In polymerizing hexafluoropropene oxide (HFPO) into a fluorinated polyether, a liquefied gas of fluorocarbon having 1 to 4 carbon atoms is added to a reactor. HFPO is polymerized in the reactor while maintaining a gas phase in the reactor under a pressure lower than the vapor pressure of the liquefied gas and allowing the liquefied gas to evaporate from the polymerization system. Heat of polymerization can be efficiently removed from the HFPO polymerization system of high viscosity, and the polymerization temperature is kept low.
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Hill, J. T., "Polymers from Hexafluoropropylene", J. Marcromol. Sci. Chem., vol. 8, No. 3 (1974) pp. 499-520.
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CA AN:117:251917, Feng et al., Controlled synthesis of . . . poly(hexafluoropropylene oxide), Sep. 1992.
CA, AN:95:204487, Duan et al., "Anionic polymerization of hexafluoropropylene oxide", Feb. 1981.
Arai Masatoshi
Kishita Hirofumi
Koike Noriyuki
Matsuda Takashi
Sato Shin'ichi
Gulakowski Randy
Shin-Etsu Chemical Co. , Ltd.
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