Polymerization of hexafluoropropene oxide

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From fluorine-containing reactant

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528408, 528421, C08G 6522, C08G 5968

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active

058177469

ABSTRACT:
In polymerizing hexafluoropropene oxide (HFPO) into a fluorinated polyether, a liquefied gas of fluorocarbon having 1 to 4 carbon atoms is added to a reactor. HFPO is polymerized in the reactor while maintaining a gas phase in the reactor under a pressure lower than the vapor pressure of the liquefied gas and allowing the liquefied gas to evaporate from the polymerization system. Heat of polymerization can be efficiently removed from the HFPO polymerization system of high viscosity, and the polymerization temperature is kept low.

REFERENCES:
patent: 3322826 (1967-05-01), Moore
patent: 3660315 (1972-05-01), Hill et al.
patent: 4303593 (1981-12-01), Kuhne
Chemical Abstracts, vol. 81, No. 6, 12 Aug. 1974, 26333.
Hill, J. T., "Polymers from Hexafluoropropylene", J. Marcromol. Sci. Chem., vol. 8, No. 3 (1974) pp. 499-520.
European Search Report.
CA AN:117:251917, Feng et al., Controlled synthesis of . . . poly(hexafluoropropylene oxide), Sep. 1992.
CA, AN:95:204487, Duan et al., "Anionic polymerization of hexafluoropropylene oxide", Feb. 1981.

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