Polymerization of fluoroolefins in presence of non-volatile poly

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Removing and recycling removed material from an ongoing...

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526 67, 526 70, 526 88, 526231, 526242, 526247, 526249, 526255, 526919, 525263, 525276, C08F 234, C08F 1418

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active

050196324

ABSTRACT:
A free-radical initiated process for preparing fluorinated polymers wherein at least one gaseous fluoroolefin is polymerized in a stirred polymerizer, the improvement comprising preparing a non-volatile polymeric seed in a reaction zone separate from the polymerizer by decomposing initiator in the presence of fluoromonomer to form oligomeric free radicals and condensing said radicals onto previously prepared polymer; and conveying said non-volatile seed to the polymerizer.

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