Polymerization of ethylene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526132, 526352, 502155, C08F 426

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active

060605693

ABSTRACT:
Certain nickel [II] complexes of selected orthophosphine substituted arylsulfonamides or selected phosphine containing alkylsulfonamides catalyze the polymerization of ethylene. The polymers produced may be used as lubricants or in waxes. Some of these nickel [II] complexes and the phosphine containing ligands are also novel compounds.

REFERENCES:
patent: 5866663 (1999-02-01), Brookhart et al.
patent: 5880241 (1999-03-01), Brookhart et al.
K. Von Issleib and K. Zimmermann: "Aminosulfonyl-alkan-phosphine" Zeitschrift Fur Anorganische Und Allgemeine Chemie, vol. 436, Dec. 1997, pp. 20-28, XP002063368.
P. Braunstein, et al., J. Chem. Soc., Dalton Trans., 1966, pp. 3571-3574.
P. Braunstein, et al., J. Chem. Soc., Dalton Trans., 1996, 3571-3524, Apr. 1996.

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