Polymerization of cyclic ethers using selected metal compound ca

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From aldehyde or derivative thereof as reactant

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528234, 528235, 528236, 528237, 528238, 528405, 528410, 528411, 528412, 528413, 528414, 528415, 528416, 568613, 568617, 568622, 568623, 568624, 568625, C08G 6516, C08G 6520, C07C 4101, C07C 4116

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056418531

ABSTRACT:
A process for polymerizing oxepanes, dioxolanes, trioxanes, and tetrahydrofurans to their respective polymers by contacting them with a selected metal compound and an accelerator which is a selected vinyl ester or a selected phosphorous compound.

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Hrkach, J.S. et al, "Cationic Polymerization of Tetrahydrofuran Initiated by Trimethylsilyl Trifluoromethanesulfonate", Macromolecules, 23, 4042-4046 (1990).
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Borkowsky, S.L. et al, "Synthesis and Chemistry of Cp.sub.2 Zr(Ph)(THF). Selectivity of Protolytic and Oxidative Zr-R Bond-Cleavage Reactions", Organometal., 10, 1268-1274 (1991).
Chem. Abstr., 78(16), 98, 119d, Misaki, T. et al, Nippon Kagaku Kaishi, (1), 168-174 (1973).

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