Polymerization of CO/olefin with two distinct temperatures

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymer of an ethylenically unsaturated reactant with a...

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C08G 6702

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050950916

ABSTRACT:
An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon in the presence of a reaction diluent and a catalyst composition formed from a palladium compound, the anion of a strong non-hydrohalogenic acid and a bidentate ligand of phosphorus, nitrogen or sulfur comprises conducting a first polymerization to produce a prepolymer and completing the polymerization at a lower temperature in the presence of sufficient prepolymer to constitute a substantial proportion of the polymerization mixture.

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