Polymerization of cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadien

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5253593, 526279, 526171, 526309, C08F13008

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active

051284189

ABSTRACT:
The monomer cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadiene can be polymerized with certain catalysts, such as bis(allyltrifluoroacetato nickel (II) and bis(allylpentafluorophenoxy nickel II). The resulting polymer is a precursor to poly(para-phenylene). Other substituted cyclohexadienes may also be polymerized by these catalysts to form useful polymers.

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patent: 4849504 (1989-07-01), Ballard et al.
Ballard, D. G. H. et al. (1988) Macromal. 21, 294-304.
McKean, D. R. et al., (1987) Macromal. 20, 1787-1792.

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