Polymerization of cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadien

Details Polymerization of cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadien Polymerization of cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadien

1992-02-05

1993-03-02

Schofer, Joseph L.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

525355, 5253591, 5253592, 525367, 525378, C08F13008

Patent

active

051910250

ABSTRACT:
The monomer cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadiene can be polymerized with certain nickel II catalysts, such as bis[(allyl)trifluoroacetatonickel(II)], bis[(allyl)pentafluorophenoxynickel(II)], and bis[(allyl)iodonickel(II)]. The resulting polymer is a precursor to poly(para-phenylene). Other substituted cyclohexadienes may also be polymerized by these catalysts to form useful polymers.

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