Polymerization of chloroprene with xanthates and dithiocarbamate

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526220, 526222, C08F 238, C08F 224

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active

048144010

ABSTRACT:
An improved process for the preparation of polychloroprene by the emulsion (co)polymerization of chloroprene and optionally other monomers capable of copolymerization with chloroprene, using a peroxo activator, and subsequent working up of the product by stopping the reaction, stabilizing, degassing and isolating the product, characterized in that polymerization is carried out in the presence of dithiocarbamates and/or xanthates and 0 to 0.5% by weight of sodium .beta.-anthraquinone sulphonate.

REFERENCES:
patent: 2426854 (1947-09-01), Bare
patent: 2430562 (1947-11-01), Fryling
patent: 3808183 (1974-04-01), Branlard
patent: 3984609 (1976-10-01), Branlard
Houben-Weyl, Methoden der Organischen Chemie, 4., Auflage (1961), pp. 351, 352.

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