Polymerization of .alpha.-pinene

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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252429R, 526190, 526281, C08F 414

Patent

active

041136535

ABSTRACT:
There is provided a process for polymerizing .alpha.-pinene by adding the same incrementally to a catalyst system comprising a major amount of an aluminum halide and a minor amount of an organo germanium halide or alkoxide in admixture with a (lower) alkyl, alkenyl or aralkyl halide in an inert solvent while controlling the temperature of reaction in the range of -30.degree. C. to +30.degree. C., drowning the polymerization mixture in water, separating the organic phase therefrom, removing the solvent therefrom, and recovering a solid polymer in good yield.

REFERENCES:
patent: 3210334 (1965-10-01), Carrick
patent: 3278508 (1966-10-01), Kahle et al.
patent: 3378539 (1968-04-01), Nowlin et al.

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