Polymerization method utilizing a three-phase emulsion system

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524459, 524460, 524801, 526199, 526200, 526201, 526202, 526203, 526207, 525366, 528 44, 528137, 528232, 528254, 528274, 528336, 528373, 528408, 524733, 524804, C08F 216, C08F 200, C08G 1800, C08G 200

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043281494

ABSTRACT:
Polymerization method utilizing a three-phase system: water-in-oil-in-water or oil-in-water-in-oil comprising the steps (a) adding the monomer material to be polymerized into the innermost water or oil phase; (b) adding, with mechanical agitation, the product of Step a to the middle oil or water phase, said phase containing appropriate surfactant, whereby an emulsion is formed; (c) adding, with mechanical agitation, the emulsion product of Step b to the outermost water or oil phase, said phase containing appropriate surfactant, wherein polymerization proceeds in the innermost water or oil phase until complete.

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patent: 4189559 (1980-02-01), Bueltjer
Matsumoto, S. et al., J. Colloid Interf. Sci., 57(2), pp. 353-361 (1976).

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