Polymerization method and t-alkyl peresters of t-hydroperoxides

Details Polymerization method and t-alkyl peresters of t-hydroperoxides Polymerization method and t-alkyl peresters of t-hydroperoxides

1973-02-20

1977-11-08

Hollrah, Glennon H.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07C17918

Patent

active

040575675

ABSTRACT:
Novel tertiary alkyl peresters of tertiary hydroperoxides are used as polymerization initiators wherein the peresters are characterized by the tertiary alkyl group of the acid moiety having at least two alkyl groups of two or more carbon atoms and the tertiary alkyl group of the hydroperoxide has at least five carbon atoms. Typical is the polymerization of certain vinyl monomers such as vinyl chloride.

REFERENCES:
patent: 2661363 (1953-12-01), Dickey
patent: 2698863 (1955-01-01), Dickey
patent: 3264274 (1966-08-01), Leveskis
patent: 3326859 (1967-06-01), Seiner
patent: 3337602 (1967-08-01), Guillet et al.
patent: 3624123 (1971-11-01), Lewis et al.
Friedman et al., "Chem. Structure vs. Activity of Peroxyesters," (1971), Mod. Plast. 48, pp. 66-68 (1971).

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