Polymerization inhibition by fullerenes

Details Polymerization inhibition by fullerenes Polymerization inhibition by fullerenes

1992-12-10

1994-04-12

Schofer, Joseph L.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526346, 526335, 526328, 526297, 526341, 526342, 526319, 526170, 526173, 526210, 526217, 526225, 558304, 558306, 558307, 560 4, 585 2, C08F 3608, C08F 1208, C07C 720

Patent

active

053026810

ABSTRACT:
The premature free-radical polymerization of a non-linear, readily polymerizable organic monomer under conditions where the monomer would otherwise polymerize is inhibited by incorporating within the non-linear, readily polymerizable monomer a polymerization inhibiting amount of a fullerene or a derivative thereof.

REFERENCES:
Article Entitled "Electron Spin Resonance Study of the Radical Reactivity of C.sub.60 " by Krusic, et al; American Chemical Society, vol. 113, No. 16, 1991 pp. 6274-6275.
Article Entitled "C.sub.60 : Buckminsterfullerene" by Kroto, et al; Chemical Reviews vol. 91, No. 6, 1991, pp. 1213-1235.
Article Entitled "C.sub.60 as a Radical Sponge" by McEwen, et al, American Chemical Society, vol. 114, No. 11, 1992, pp. 4412-4415.
Article Entitled "Synthesis of a C.sub.60 -p-Xylylene Copolymer" by Loy, et al, American Chemical Society, vol. 114, 1992, pp. 3977-3978.
Article Entitled "Systematic Chemistry of C.sub.60 Beginning To Emerge" by Rudy Baum, C&EN, 1991, pp. 17-20.
Article Entitled "Great Balls of Carbon" by Brian Nadel, Chemical Business, 1992, pp. 15-17.
Article Entitled "Buckyballs: Wide Open Playing Field For Chemists", Science, vol. 254, 1991, pp. 1706-1707.
Article Entitled "The Chemical Properties of Buckminsterfullerene (C.sub.60) and the Birth and Infancy of Fulleroids" by Fred Wudl; Acc. Chem. Res. 1992, vol. 25, pp. 157-161.
Article Entitled "Radical Reactions of C.sub.60 " by Krusic, et al; Science, 1991; vol. 254, pp. 1183-1185.
Article Entitled "Fullerenes" by Curl, et al; Scientific American, 1991, pp. 54-63.

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