Polymerization catalysts

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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Details

252429C, 526127, 526139, 526144, 526116, 526122, 526151, C08F 464

Patent

active

042870917

ABSTRACT:
Polymerization, catalysts, and preparation thereof comprising milling magnesium metal, an organic halide, and titanium tetrahalide or the milled product in the presence of at least one of magnesium oxide, a triaryl phosphite, a polymeric material, titanium tetrahalide, vanadium tetrahalide, silicon tetrahalide, and an aluminum trihalide. The milled catalyst component can be heat treated prior to activation. The milled titanium catalyst component is activated with an organoaluminum activator producing a catalyst for olefin polymerization.

REFERENCES:
patent: 3412174 (1968-11-01), Kroll
patent: 3718635 (1973-02-01), Tomoshier et al.
patent: 3781220 (1973-12-01), Shilov et al.
patent: 3801558 (1974-04-01), Fletcher et al.
patent: 4048415 (1977-09-01), Matsuzawa et al.
patent: 4098907 (1978-07-01), Tokunaga et al.

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